• Canada
• 2013-2022close
• 2016 close

Efficient air traffic management depends on reliable communications between aircraft and the air traffic control centres. However there is a lack of ground infrastructure in the Arctic to support communications via the standard VHF links (and over the Arctic Ocean such links are impossible) and communication via geostationary satellites is not possible above about 82 degrees latitude because of the curvature of the Earth. Thus for the high latitude flights it is necessary to use high frequency (HF) radio for communication. HF radio relies on reflections from the ionosphere to achieve long distance communication round the curve of the Earth. Unfortunately the high latitude ionosphere is affected by space weather disturbances that can disrupt communications. These disturbances originate with events on the Sun such as solar flares and coronal mass ejections that send out particles that are guided by the Earth's magnetic field into the regions around the poles. During such events HF radio communication can be severely disrupted and aircraft are forced to use longer low latitude routes with consequent increased flight time, fuel consumption and cost. Often, the necessity to land and refuel for these longer routes further increases the fuel consumption. The work described in this proposal cannot prevent the space weather disturbances and their effects on radio communication, but by developing a detailed understanding of the phenomena and using this to provide space weather information services the disruption to flight operations can be minimised. The occurrence of ionospheric disturbances and disruption of radio communication follows the 11-year cycle in solar activity. During the last peak in solar activity a number of events caused disruption of trans-Atlantic air routes. Disruptions to radio communications in recent years have been less frequent as we were at the low phase of the solar cycle. However, in the next few years there will be an upswing in solar activity that will produce a consequent increase in radio communications problems. The increased use of trans-polar routes and the requirement to handle greater traffic density on trans-Atlantic routes both mean that maintaining reliable high latitude communications will be even more important in the future.

Carbon capture and storage (CCS) has emerged as a promising means of lowering CO2 emissions from fossil fuel combustion. However, concerns about the possibility of harmful CO2 leakage are contributing to slow widespread adoption of the technology. Research to date has failed to identify a cheap and effective means of unambiguously identifying leakage of CO2 injected, or a viable means of identifying ownership of it. This means that in the event of a leak from a storage site that multiple operators have injected into, it is impossible to determine whose CO2 is leaking. The on-going debate regarding leakage and how to detect it has been frequently documented in the popular press and scientific publications. This has contributed to public confusion and fear, particularly close to proposed storage sites, causing the cancellation of several large storage projects such as that at Barendrecht in the Netherlands. One means to reduce public fears over CCS is to demonstrate a simple method which is able to reliably detect the leakage of CO2 from a storage site and determine the ownership of that CO2. Measurements of noble gases (helium, neon, argon, krypton and xenon) and the ratios of light and heavy stable isotopes of carbon and oxygen in natural CO2 fields have shown how CO2 is naturally stored over millions of years. Noble gases have also proved to be effective at identifying the natural leakage of CO2 above a CO2 reservoir in Arizona and an oil field in Wyoming and in ruling out the alleged leakage of CO2 from the Weyburn storage site in Canada. Recent research has shown amounts of krypton are enhanced relative to those of argon and helium in CO2 captured from a nitrate fertiliser plant in Brazil. This enrichment is due to the greater solubility of the heavier noble gases, so they are more readily dissolved into the solvent used for capture. This fingerprint has been shown to act as an effective means of tracking CO2 injected into Brazilian and USA oil fields to increase oil production. Similar enrichments in heavy noble gases, along with high helium concentrations are well documented in coals, coal-bed methane and in organic rich oil and gas source rocks. As noble gases are unreactive, these enrichments will not be affected by burning the gas or coal in a power station and hence will be passed onto the flue gases. Samples of CO2 obtained from an oxyfuel pilot CO2 capture plant at Lacq in France which contain helium and krypton enrichments well above atmospheric values confirm this. Despite identification of these distinctive fingerprints, no study has yet investigated if there is a correlation between them and different CO2 capture technologies or the fossil fuel being burnt. We propose to measure the carbon and oxygen stable isotope and noble gas fingerprint in captured CO2 from post, pre and oxyfuel pilot capture plants. We will find out if unique fingerprints arise from the capture technology used or fuel being burnt. We will determine if these fingerprints are distinctive enough to track the CO2 once it is injected underground without the need of adding expense artificial tracers. We will investigate if they are sufficient to distinguish ownership of multiple CO2 streams injected into the same storage site and if they can provide an early warning of unplanned CO2 movement out of the storage site. To do this we will determine the fingerprint of CO2 captured from the Boundary Dam Power Plant prior to its injection into the Aquistore saline aquifer storage site in Saskatechwan, Canada. By comparing this to the fingerprint of the CO2 produced from the Aquistore monitoring well, some 100m from the injection well, we will be able to see if the fingerprint is retained after the CO2 has moved through the saline aquifer. This will show if this technique can be used to track the movement of CO2 in future engineered storage sites, particularly offshore saline aquifers which will be used for future UK large volume CO2 storage.