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Other research product . Other ORP type . 2018

Redundant Coordinates in Quantum Mechanics

Toombs, Eric; Carrington, Tucker Jr;
English
Published: 01 Jan 2018
Country: Canada
Abstract

We present a kinetic energy operator and inner product that can be used to solve the Schroedinger equation in redundant coordinates. The goal is to develop equations and a computational procedure that can be used with N coordinates for a system with M degrees of freedom, where N > M. In chemical physics, this might be useful for exploiting symmetry or exploiting certain representations of potentials. Calculations demonstrate that the ideas work.

Subjects

Schroedinger Equation, Kinetic Energy Operator, Quantum Mechanics

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Other ORP type . 2018
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