research product . Other ORP type . 2016

Nickel(II), copper(I) and zinc(II) complexes supported by a (4-diphenylphosphino)phenanthridine ligand

Mondal, Rajarshi; Giesbrecht, Patrick; Herbert, David E;
Open Access English
  • Published: 29 Mar 2016
  • Publisher: Elsevier
  • Country: Canada
Abstract
A synthetic route to 4-bromophenanthridine has been devised, enabling the construction of (4-diphenylphosphino)phenanthridine (1), a heterobifunctional Lewis base containing both phosphine and phenanthridine donors. The coordination chemistry of 1 with ions of late first-row transition metals nickel, copper and zinc has been explored, leading to the isolation and characterization of an organometallic Ni(II) complex, chloro(1-naphthyl)[(4-diphenylphosphino)phenanthridine]nickel (2), a halide-bridged copper(I) complex, bromo[(4-diphenylphosphino)phenanthridine]copper dimer (3), and a Zn(II) complex, bis(chloro)[(4-diphenylphosphino)phenanthridine]zinc (4). The sol...
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free text keywords: Ligand design
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